We already mentioned Greg Maddux, so why stop at just one of the Atlanta Braves greats? After all, in '96, John Smoltz led the league with a WAR of 8.4 on a FIP of 2.64 with 9.79 strikeouts per nine. He won 24 games in his 35 starts.
Naturally, Smoltz won the Cy Young and was voted to the fourth All-Star Game of his career.